Improved Resistance to Neck-Liner Impingement in Second-Generation Highly Crosslinked Polyethylene—The Role of Vitamin E and Crosslinks

Radiation crosslinking of ultrahigh molecular weight polyethylene (UHMWPE) results in the reduced tensile strength and fracture toughness as an expense of dramatic increase in the wear resistance. Clinical rim fracture has been reported due to neck-liner impingement on a first-generation highly crosslinked UHMWPE acetabular component. The objective of this study was to investigate whether a second-generation, vitamin E–blended highly crosslinked UHMWPE possesses the improved impingement resistance.

Cyclic impingement testing was performed in a variety of UHMWPE acetabular components (vitamin E free or blended, noncrosslinked or highly crosslinked, and GUR1050 or GUR1020) with the same design specification. The kinematics used to reproduce the neck-liner impingement was a uniaxial fatigue compression in concert with an axial rotational torque. After the test, the geometry and morphological changes were characterized by coordinate measuring machine, scanning electron microscopy, and confocal Raman microspectroscopy.

A total of 300-kGy irradiated and annealed GUR1050 liner resulted in a significant geometry change and microcracks on the rim surface after the test. However, regardless of the similar level of crosslinking, much less damage was noted in the 300-kGy irradiated GUR1050 liner blended with vitamin E at a concentration of 3000 ppm. On the other hand, vitamin E–blended noncrosslinked GUR1050 exhibited an extensive microscopic fibrillation and folding on the impinged surface.

These results suggest that vitamin E–blending into UHMWPE has compensated the negative effect of toughness decrease induced by radiation crosslinking. We concluded that the coexistence of vitamin E and crosslinks can restrain impingement damage more effectively than either of them.